聚己内酰胺微孔注塑发泡:纳米成核剂的影响
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国家重点研发计划(2016YFB0302200)


Microcellular Injection Foaming of Polycaprolactam: Effect of Nano Nucleating Agents
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    摘要:

    将几种纳米成核剂分别与线型PA6(L-PA6)和长链支化PA6(LCB-PA6)共混制得纳米复合材料。通过流变行为表征发现,纳米成核剂对于L-PA6的流变行为影响不大,但显著提高了LCB-PA6的熔体强度;通过非等温结晶动力学表征发现,纳米石墨与碳纳米管可有效提高PA6的结晶速率和结晶温度;通过泡孔形貌表征发现,加入纳米石墨对L-PA6的发泡性能提升最大,250 ℃的泡孔密度为1.66×107 cm-3,达到L-PA6纯树脂的3倍以上,加入碳纳米管对LCB-PA6的异相成核效果最好,且可有效降低LCB-PA6对发泡温度的依赖性;通过力学性能测试发现,碳管与LCB-PA6的界面结合力较低导致LCB-PA6成核改性发泡材料表现出较低的拉伸模量与弯曲模量;而羧基化碳纳米管由于表面羟基的极性,增大了其与LCB-PA6的界面结合力,显著提高了LCB-PA6的拉伸模量与弯曲模量;纳米石墨由于其高强度层状结构,对L-PA6的拉伸模量与弯曲模量提升巨大。

    Abstract:

    Several nano-nucleating agents were blended with linear PA6 (L-PA6) and long-chain branched PA6 (LCB-PA6) to prepare nanocomposites. The rheological behavior characterization founds that the nano-nucleating agent has little effect on the rheological behavior of L-PA6, but significantly improves the melt strength of LCB-PA6. The non-isothermal crystallization kinetic characterization founds that nanographite and MWCNTs can effectively improve the crystallization rate and crystallization temperature of PA6. Through the characterization of the cell morphology, it is found that the addition of nanographite has the greatest improvement in the foaming performance of L-PA6. The cell density of which at 250 ℃ is 1.66×107 cm-3, which achieves more than 3 times of pure resin. The effect of adding MWCNTs on the heterophasic nucleation of LCB-PA6 is the best, which can effectively reduce the dependence of LCB-PA6 on foaming temperature. Through mechanical property test, it is found that the low interface binding force between carbon tube and LCB-PA6 results in lower tensile modulus and flexural modulus for the LCB-PA6 nucleated modified foamed material. Due to the polarity of the hydroxyl groups on the surface of MWCNTs-OH, the interface binding force with LCB-PA6 is increased, and the tensile modulus and flexural modulus of LCB-PA6 are significantly improved. Due to the high-strength layered structure of nano-graphite, the tensile modulus and flexural modulus of L-PA6 are greatly improved.

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韩翔宇, 刘 涛, 赵 玲.聚己内酰胺微孔注塑发泡:纳米成核剂的影响[J].高分子材料科学与工程,2021,37(3):106-113.

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