耐温抗盐半互穿PVP-in situ-PVA水凝胶的研制与性能调控
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中国石油化工股份有限公司胜利油田勘探开发研究院,山东 东营 257015

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国家科技重大专项(2025ZD1407100);泰山产业领军人才项目(tscx 202306048);中国石化新领域培育项目(P24016)


Development and Performance Modulation of High-Temperature and Salt-Resistant Semi-Interpenetrating PVP-In Situ-PVA Hydrogel
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    摘要:

    油田开采后期,地层深处的高温高盐环境加剧,现有聚合物驱油剂难以满足石油增产增收的使用要求。为制备满足严苛地层环境的聚合物驱油剂,采用构筑半互穿网络结构的策略,以聚乙烯基吡咯烷酮(PVP)为线型聚合物,环氧氯丙烷(ECH)交联的聚乙烯醇(PVA)为交联网络,制备了耐温抗盐的半互穿PVP-in situ-PVA水凝胶,研究了其对温度和不同矿化度盐水的耐受性,并对其网络结构和性能进行分析。结果表明,当ECH和PVP质量分数分别为1.7wt%和0.67wt%时,PVP-in situ-PVA水凝胶的压缩强度最佳,为0.30 MPa,且PVP用量对PVP-in situ-PVA水凝胶力学性能及耐温抗盐性能有显著影响。进一步制备的粘弹性颗粒驱油剂PVP0.67/PVA PPG在90 ℃老化20天后模量保留率仍有46.2%,优于未加入PVP的PVP0/PVA PPG。

    Abstract:

    In the later stages of oilfield production, the high-temperature, high-salinity environment deep within the formation intensifies, making it difficult for existing polymer oil displacement agents to meet the requirements for increasing oil production and revenue. To develop polymer oil recovery agents capable of withstanding these harsh reservoir conditions, a strategy was adopted to construct a semi-interpenetrating network structure. Polyvinylpyrrolidone (PVP) was used as the linear polymer, and polyvinyl alcohol (PVA) crosslinked with epichlorohydrin (ECH) served as the crosslinking network, resulting in a temperature- and salt-resistant semi-interpenetrating PVP-in situ-PVA hydrogel. The hydrogel’s tolerance to temperature and brine of varying salinities was investigated, and its network structure and properties were analyzed. The results indicate that when the mass fractions of ECH and PVP are optimized to 1.7 wt% and 0.67 wt%, respectively, the PVP-in situ-PVA hydrogel exhibits the highest compressive strength of 0.30 MPa. Furthermore, the PVP content significantly influences the mechanical properties and thermal and salt resistance of the PVP-in situ-PVA hydrogel. The viscoelastic particle oil displacement agent PVP0.67/PVA PPG prepared in this study retains 46.2% of its modulus after aging at 90 °C for 20 d, outperforming the PVP0/PVA PPG without PVP.

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  • 收稿日期:2025-07-26
  • 录用日期:2026-03-18
  • 网络出版日期:2026-07-14
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