芳纶纤维/聚酰亚胺复合气凝胶的制备及声学性能
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武汉工程大学 材料科学与工程学院 湖北省等离子体化学与新材料重点实验室, 湖北 武汉430205

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湖北省重点研发计划 (2023BAB001)


Preparation and Acoustic Properties of Aramid Fiber/Polyimide Composite Aerogel
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    摘要:

    聚酰亚胺气凝胶(PI)作为一种高性能聚合物材料,在声热防护方面有着巨大的应用前景,然而纯PI存在孔结构单一,声学和力学性能较差的问题限制了其在降噪领域应用。为了提升PI气凝胶的综合性能并且拓展其应用范围,通过将芳纶纤维(ANF)分散体与聚酰亚胺酸(PAA)混合,采用冷冻干燥、热亚胺化处理的方法制备了一种低收缩、高强度、吸声性能良好的聚酰亚胺-芳纶纤维气凝胶(PI-ANF)。ANF加入后,气凝胶样品的收缩率由PI纯样的37.4%逐步降低至PI-ANF-8的30.0%,而最大压缩强度由PI的20.3 kPa提升至PI-ANF-8的104 kPa,PI-ANF最低分解温度为430 °C,依然支持气凝胶在400 °C以下的较高温度下使用。当ANF含量为3 wt%时,附着在PI骨架内的ANF构建了大量介孔可以有效吸收声波,使复合气凝胶的声学性能达到最佳,平均吸声系数可达0.78。结果表明,ANF引入后有效提高了PI气凝胶吸声性能和力学性能,在新能源和建筑材料领域具有一定应用价值。

    Abstract:

    As a high-performance polymer material, polyimide (PI) aerogel holds great promise for applications in acoustic and thermal protection. However, PI suffers from a monotonous pore structure and poor acoustic and mechanical properties, which limit its use in noise reduction. To enhance the overall performance of PI aerogels and expand their scope of application, a polyimide-aramid fiber aerogel (PI-ANF) with low shrinkage, high strength, and excellent sound-absorbing properties was prepared by mixing an aramid fiber (ANF) dispersion with polyimide acid (PAA) and subjecting the mixture to freeze-drying and thermal imidization. Following the incorporation of ANF, the shrinkage rate of the aerogel samples gradually decreases from 37.4% in the pure PI sample to 30.0% in the PI-ANF-8 sample, while the maximum compressive strength increases from 20.3 kPa in PI to 104 kPa in PI-ANF-8. The minimum decomposition temperature of PI-ANF is 430 °C, which still allows the aerogel to be used at relatively high temperatures below 400 °C. When the ANF mass fraction is 3%, ANF incorporated into the PI matrix forms a large number of mesopores capable of effectively absorbing sound waves, optimizing the acoustic performance of the composite aerogel and achieving an average sound absorption coefficient of 0.78. The results indicate that the introduction of ANF effectively enhances both the sound absorption and mechanical properties of PI aerogels, demonstrating significant application potential in the fields of new energy and building materials.

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  • 收稿日期:2025-08-26
  • 录用日期:2026-03-16
  • 网络出版日期:2026-08-17
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