热压罐成型压力对双马树脂基复合材料孔隙及力学性能的影响
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Effect of Forming Pressure of Autoclave on Voids and Mechanical Properties of Bismaleimide Resin Composites
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    摘要:

    双马来酰亚胺树脂(BMI)具有良好的加工工艺性能和优异的耐热性能,以BMI为基体的复合材料近些年在航空航天领域应用广泛。文中采用热压罐工艺固化T800/双马树脂基预浸料,设置0.1~ 0.8 MPa的成型压力,制备了[0/90/±45]2s及[0]14铺层的不同孔隙率的层合板。通过显微镜法表征了孔隙率和孔隙的尺寸、形状及分布。针对2种铺层和不同孔隙率样件的力学性能,开展了拉伸、弯曲和层间剪切实验,并采用扫描电子显微镜技术观察了受影响程度最大的层间剪切样件的失效形貌。结果表明,低成型压力会使孔隙突变,孔隙尺寸增大,并从层内向层间分布,导致力学性能急剧降低,其中,层间剪切性能受孔隙突变影响最大。当成型压力从0.8 MPa降低至0.1 MPa时,[0/90/±45]2s铺层试样层间剪切强度下降26.22%,经失效分析认为,这是由于层间的大尺寸孔隙造成的性能降低。

    Abstract:

    Bismaleimide resin (BMI) has good processing properties and excellent heat resistance. Composites based on BMI have been widely used in aerospace field in recent years. In this study, T800/BMI composites were cured by autoclave process. Laminates with different void content of [0/90/±45]2s and [0]14 layers were prepared by setting the forming pressure of 0.1~ 0.8 MPa. The void content, size, shape and distribution were characterized by microscopy. The tensile, bending and interlayer shear tests were carried out for the mechanical properties, and the failure morphology of the interlayer shear samples was observed by scanning electron microscopy. The results show that low forming pressure will cause void mutation, void size increase, and distribution from intralayer to interlayer, resulting in a sharp decrease in mechanical properties, among which the interlayer shear performance is most affected by void mutation. When the molding pressure is reduced from 0.8 MPa to 0.1 MPa, the interlayer shear strength of the [0/90/±45]2s specimen is decreased by 26.22%, which is due to the large-size voids between the layers.

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刘梓楠,于雅琳,王 荣,孙宏杰,周何乐子,黄志高,周华民.热压罐成型压力对双马树脂基复合材料孔隙及力学性能的影响[J].高分子材料科学与工程,2025,41(2):70-77. Zinan Liu, Yalin Yu, Rong Wang, Hongjie Sun, Helezi Zhou, Zhigao Huang, Huamin Zhou. Effect of Forming Pressure of Autoclave on Voids and Mechanical Properties of Bismaleimide Resin Composites[J]. Polymer Materials Science & Engineering,2025,41(2):70-77.

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