微型注塑加工条件下聚甲醛/尼龙11/碳纳米管复合材料的结晶形貌及充填行为
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国家自然科学基金资助项目(51010004);高等学校学科创新引智计划(B13040)


Crystallization, Morphology and Filling Behavior of Polyoxymethylene/Polyamide 11/Carbon Nanotubes Composites Under Micro Injection Molding Conditions
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    摘要:

    文中将与聚甲醛(POM)加工温度接近的工程塑料尼龙11 (PA11)引入POM/碳纳米管(CNTs)体系制备POM/PA11/CNTs三元复合材料,研究相应微型注塑和常规注塑样品中PA11、CNTs等分散相的形貌结构及不同微型注塑加工条件下的结晶熔融行为和充填行为。扫描电子显微镜分析表明,常规样品中PA11呈椭球状无规分散于POM基体树脂中,而在微型样品中PA11呈现多层次结构,在皮层和剪切层区域PA11形成纤状结构并沿熔体流动方向取向,在芯层区域的成纤及取向程度则明显减弱。此外,无论对微型样品还是常规样品,大多数CNTs均选择性分散于PA11分散相中。差示扫描量热分析结果表明,PA11的加入抑制了POM的结晶,随注射速度和模具温度的升高,POM的熔融峰向高温方向移动。最后,利用微型注塑机获得的在线数据研究了三元复合体系在微型模腔中的充填行为。

    Abstract:

    The engineering plastic nylon 11 (PA11) with a processing temperature close to polyoxymethylene (POM) was introduced to the POM/carbon nanotubes (CNTs) system to prepare POM/PA11/CNTs ternary composite. The morphology structure of the dispersed phases including PA11 and CNTs in the corresponding micro part and the conventional macropart samples, the crystallization melting behavior and the filling behavior under the different micro injection processing conditions were investigated. The SEM results show that in the conventional injection molded samples, the PA11 phases, which are present as many ellipsoidal particles, are irregularly distributed in the POM matrix resin. However, in the micropart, the distribution of PA11 phases shows multi hierarchy structural features. In the skin layer and the shear layer of the samples, there are many fibrillar structures of PA11 phases formed, which are orientated along the melt flow direction. In the core layer, the degrees of the fibrillation and also the orientation of PA11 phases obviously become weakened. In addition, whether for the micropart or the conventional macropart, most of the involved CNTs are either selectively dispersed in the PA11 dispersed phase. The DSC results show that the addition of PA11 restrict the POM crystallization. With increase in injection speed or mold temperature, the corresponding melting peak of POM equally shifts toward high temperature. Finally, the filling behavior of above ternary composite system in the micro cavity was also investigated by the on line measurement of the micro molding machine.

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蒋芝, 陈英红, 刘卓.微型注塑加工条件下聚甲醛/尼龙11/碳纳米管复合材料的结晶形貌及充填行为[J].高分子材料科学与工程,2014,30(9):69-73. Zhi Jiang, Yinghong Chen, Zhuo Liu. Crystallization, Morphology and Filling Behavior of Polyoxymethylene/Polyamide 11/Carbon Nanotubes Composites Under Micro Injection Molding Conditions[J]. Polymer Materials Science & Engineering,2014,30(9):69-73.

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