仿生自修复涂层研究进展
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东北石油大学 化学化工学院 黑龙江省石油与天然气化工省重点实验室,黑龙江 大庆 163318

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东北石油大学引导性创新基金项目(15071202128);东北石油大学人才引进科研启动经费项目(13051202104);黑龙江省自然科学基金资助项目(LH2023E013)


Progress on Research of Bionic Self-Healing Coatings
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    摘要:

    传统基于热固型材料的涂层,一旦破坏失效,难以修复,会对设备生产安全带来严重隐患,另外涂层频繁的维修也带来了大量的经济损失。随着科学技术的发展,仿生自修复涂层作为一种新兴的智能材料,是近年来材料领域的研究热点之一。本文综述了本征型自修复防腐涂层的研究进展。按自愈机理分,自修复材料分为外援型和本征型自修复材料2种。外援型包括微胶囊和微血管型,本征型包括狄尔斯-阿尔得反应、可逆二硫键、酯交换、氢键、主客体相互作用等。重点论述了本征型自修复涂层材料的类型(基于可逆动态共价键和可逆非共价键的自愈)、研究现状及目前存在的问题,阐述了自修复涂层在防腐、自清洁、导电等领域的应用,并对自修复涂层的研究方向和发展前景进行了展望。

    Abstract:

    Traditional coatings based on thermosetting materials, are difficult to repair once damaged and failed, which will bring serious risks to the production safety of equipment. And the frequent maintenance of coating also brings a lot of economic losses. With the development of science and technology, bionic self-healing coating, as a new intelligent material, has become one of the research hotspots in the field of materials in recent years. The research progress of intrinsic self-healing anticorrosive coatings was reviewed. According to the self-healing mechanism, self-healing materials can be divided into two types: external aid type and intrinsic type. External type includes microcapsule and microvascular type, intrinsic type includes Diels-Alder reaction, reversible disulfide bond, transesterification, hydrogen bond, host-guest interaction and so on. The types of intrinsic self-healing coating materials based on reversible dynamic covalent bond and reversible non-covalent bond self-healing, research status and existing problems were discussed. The applications of self-repairing coating in the fields of anti-corrosion, self-cleaning and electric conduction were described. The research direction and development prospect of self-repairing coating were also prospected.

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  • 收稿日期:2024-05-24
  • 录用日期:2024-09-14
  • 网络出版日期:2024-10-22
  • 在线发布日期: 2024-12-04
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