基于扩展有限元的力学性能配比对微胶囊可裂性的影响
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国家自然科学基金资助项目(52365057);温州市科技计划项目(G2023045);甘肃省科技重大专项(23ZDGE002)


Influence of Mechanical Property Proportioning Based on Extended Finite Element on the Rupturability of Microcapsules
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    摘要:

    针对微胶囊能否及时开裂,释放愈合剂从而修复基体中产生的微裂纹以确保良好自愈性能的问题,文中采用扩展有限元方法结合内聚力模型,建立了含预制裂纹和微胶囊的三维数值模型,从微观角度分析了基体开裂与微胶囊开裂的过程及其内在机理。然后以微胶囊与环氧树脂基体之间弹性性能比、断裂性能比及核壳比和界面强度为变量,揭示其对微胶囊可裂性的影响。结果表明:(1) 微胶囊的开裂取决于微胶囊与基体的弹性性能比和断裂性能比的结合,其中断裂性能比起主要作用;(2) 在微胶囊与基体弹性性能比相同的情况下,核壳比越大微胶囊越容易裂开;(3) 微胶囊与基体之间的界面强度较高有助于微胶囊的开裂。研究结果为微胶囊可裂性设计提供了参考依据,为自修复复合材料的应用提供理论指导。

    Abstract:

    To address the problem of whether microcapsules can crack in time and release healing agents to repair the microcracks generated in the matrix to ensure excellent self- healing performance, the study combined with a cohesion model to establish a three- dimensional numerical model containing prefabricated cracks and microcapsules through XFEM, and analyzed the process of matrix cracking and microcapsule cracking besides its intrinsic mechanism from a microscopic point of view. The research focused on the ratios of elastic properties, fracture properties, core-shell ratios, and interfacial strength between microcapsules and the epoxy resin matrix, to elucidate their impact on crack propagation paths and the crackability of microcapsules. The results show that: (1) the cracking of microcapsules primarily depends on their ratios of elastic and fracture properties with the matrix, particularly the latter having a more significant effect on the microcapsule cracking; (2) at the same elastic property ratios, a larger core-shell ratio facilitates easier cracking of microcapsules; (3) the high interface strength between microcapsules and matrix facilitates the cracking of microcapsules. These findings offer crucial insights for the design of crackability in microcapsules and provide theoretical guidance for the application of self-repairing composite materials.

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王若彤,郭润兰,黄 华,李 辉.基于扩展有限元的力学性能配比对微胶囊可裂性的影响[J].高分子材料科学与工程,2025,41(1):114-124. Ruotong Wang, Runlan Guo, Hua Huang, Hui Li. Influence of Mechanical Property Proportioning Based on Extended Finite Element on the Rupturability of Microcapsules[J]. Polymer Materials Science & Engineering,2025,41(1):114-124.

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  • 在线发布日期: 2025-04-02
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