基于Vitrimer 树脂的纤维增强复合材料研究进展
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国家自然科学基金资助项目(52303164)


Progress on Research of Fiber Reinforced Composites Based on Vitrimer Resins
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    摘要:

    纤维增强树脂基复合材料因其质轻、高强、可设计性强等特点在航空航天、汽车、轨道交通等诸多领域占据着重要地位,成为先进结构轻量化的重要技术途径。然而,传统的热固性树脂基体,如环氧树脂,其聚合物网络中不可逆的三维交联结构导致材料在损坏或超期服役时无法有效修复或回收,造成了严重的能源浪费和环境污染问题。类玻璃高分子(Vitrimer)树脂的出现为从材料源头解决传统热固性树脂基复合材料不可修复及难回收问题提供了有效途径。文中从动态化学键分类的角度综述了纤维增强Vitrimer 树脂基复合材料的最新研究进展,主要包括酯交换反应、亚胺键、双硫键、氨基交换反应、硼酸酯键。讨论了基于不同交换化学反应构建的复合材料体系的制备方法、性能特点及再生回收方法,对其存在的优缺点及发展趋势进行了归纳总结,旨在为纤维增强Vitrimer 树脂基复合材料的研究和应用提供参考。

    Abstract:

    Fiber reinforced resin matrix composites have been widely used in automobiles, aerospace industry, sporting goods and other important frontiers, due to their advantageous properties such as high stiffness and strength, low density, and flexible structural design. However, because of their permanent cross-linked networks of the thermosetting resin matrixes, the composites are difficult to be recycled or repaired effectively, which give rise to serious environmental pollution and tremendous waste of resources. The development of vitrimers provides an effective way to address the recycling and repairing issues of fiber reinforced thermosetting composites from the source of matrix resin, thus the carbon fiber reinforced composites based on vitrimers have also attracted increasing attention in recent years. Compared with traditional thermosetting composites, the vitrimer-based composites can not only exhibit comparable mechanical and thermal properties, but also can achieve recyclability, repairability and reshapeability functions, showing great application prospects and broad market in the current carbon neutral background. The recent developments of fiber reinforced vitrimer resin composites based on different exchange mechanisms such as transesterification, imine bonds, disulfide exchange, transamination of vinylogous urethanes and boronic ester bonds were reviewed. The preparation method, characteristics, recycling mechanisms and methods of vitrimer-based composites were discussed, and the development prospect and challenge were summarized. This review aims to provide reference for the further research and application of fiber reinforced vitrimer resin matrix composites.

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汪 东, 胡竹峰, 李 琪, 张 洋, 王天娇, 李丽英.基于Vitrimer 树脂的纤维增强复合材料研究进展[J].高分子材料科学与工程,2026,42(1):151-160. Dong Wang, Zhufeng Hu, Qi Li, Yang Zhang, Tianjiao Wang, Liying Li. Progress on Research of Fiber Reinforced Composites Based on Vitrimer Resins[J]. Polymer Materials Science & Engineering,2026,42(1):151-160.

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