基于动态缠结网络的应变温度传感器的制备及性能
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国家自然科学基金青年基金资助项目(52303162);山西省基础研究计划资助项目(202203021222046)


Fabrication and Performance of Strain and Temperature Sensors Based on Dynamic Entanglement Networks
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    摘要:

    针对柔性传感器领域对兼具优异力学性能与多模态传感功能材料的迫切需求,文中合成了一种基于羧甲基纤维素钠大分子交联剂的温敏型导电水凝胶,系统优化了合成工艺,解析了结构-性能关系,并验证了其在人体运动监测与健康管理中的双模态传感潜力。 通过一步接枝反应,制得了可以将化学交联网络和动态缠结网络同时整合到水凝胶的新型交联剂。 水凝胶兼具出色的力学性能和电导率,在 25% ~ 300% 应变范围内响应时间短于 1 s,100 次循环后ΔR/R0波动低于 5% ,可实时监测关节弯曲动作。 同时,该水凝胶的低临界共溶温度与人体体温吻合,可实现发热异常可视化预警。

    Abstract:

    Addressing the urgent demand in the field of flexible sensors for materials that combine excellent mechanical properties with multimodal sensing capabilities, in this study, a thermoresponsive conductive hydrogel based on sodium carboxymethyl cellulose ( CMC )-derived macromolecular crosslinker was designed and synthesized. The synthesis process was systematically optimized, and the structure-property relationships were thoroughly analyzed to validate its bimodal sensing potential in human motion monitoring and health management. A novel crosslinking agent was prepared via one-step grafting reaction, enabling the simultaneous integration of chemically crosslinked networks and dynamically entangled networks within the hydrogel. The resulting material exhibits outstanding mechanical performance and electrical conductivity. In the strain range of 25% ~ 300% , the response time is less than 1 s, with a relative resistance change (ΔR/R0) fluctuation below 5% after 100 cycles, demonstrating its capability for real-time monitoring of joint bending motions. Furthermore, the lower critical solution temperature of the hydrogel is consistent with the range of human body temperature, enabling visualized early warning of fever anomalies.

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杜文浩, 李帅成, 赵志新, 张 熙.基于动态缠结网络的应变温度传感器的制备及性能[J].高分子材料科学与工程,2026,42(3):71-80. Wenhao Du, Shuaicheng Li, Zhixin Zhao, Xi Zhang. Fabrication and Performance of Strain and Temperature Sensors Based on Dynamic Entanglement Networks[J]. Polymer Materials Science & Engineering,2026,42(3):71-80.

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  • 在线发布日期: 2026-05-30
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