植酸-抗坏血酸钙协同改性明胶复合膜的制备及性能
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国家自然科学基金资助项目(52303080);河南省重点研发与推广专项(科技攻关) (232102110133,232102111062,242102230126,262102110148);河南省高等学校重点科研项目(24B220002)


Preparation and Properties of Gelatin Composite Films Synergistically Modified with Phytic Acid and Calcium Ascorbate
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    摘要:

    为改善明胶薄膜的基本性能并增强其功能性,采取双重交联策略,引入植酸和抗坏血酸钙协同交联改性明胶,并通过流延法制备了明胶复合薄膜。 通过扫描电镜、傅里叶变换红外光谱及 X 射线衍射分析证实了植酸和抗坏血酸钙对明胶的协同交联作用。 进一步通过拉伸试验、紫外可见吸收光谱、水蒸气透过率测试、热重分析及 DPPH 自由基清除率测试等方法研究了复合薄膜的综合性能。 结果表明,植酸的引入显著提升了明胶薄膜的力学性能和阻隔性能,与纯明胶膜相比,其拉伸强度最大为 64.17 MPa,提高了 37% ,水蒸气透过率降低 28.3% 。 抗坏血酸钙的引入进一步增强了复合膜的热稳定性和抗紫外性能,赋予薄膜高效的抗氧化能力,复合薄膜起始分解温度提高至 294.8 ℃,实现了对 350 nm 以下紫外线的完全屏蔽,其 DPPH 自由基清除率可达 76.9% 。 植酸与抗坏血酸钙协同改性有效提高了明胶薄膜的综合性能,为功能型明胶复合膜的开发提供了技术参考。

    Abstract:

    To improve the fundamental properties and enhance the functionality of gelatin films, a dual crosslinking strategy was employed to modify gelatin by synergistically incorporating phytic acid ( PA) and calcium ascorbate (CA), with composite films fabricated via solution casting method. SEM, FT-IR and XRD analyse confirmed the synergistic crosslinking interaction of PA and CA within the gelatin networks. The comprehensive properties of the composite films were systematically investigated through tensile tests, UV-vis spectroscopy, water vapor permeability ( WVP) measurements, thermogravimetric analysis, and DPPH radical scavenging assays. Results demonstrate that the incorporation of PA significantly enhances the mechanical and barrier properties of gelatin films. Compared with pure gelatin film, the optimized composite film exhibits a 37% increase in the maximum tensile strength (64.17 MPa) and a 28.3% reduction in WVP. The supplementation of CA not only improves the thermal stability and UV-blocking performance, but also endows the film with remarkable antioxidant activity. The initial decomposition temperature of the composite film increases to 294.8 ℃, and complete UV shielding capacity is achieved for wavelengths below 350 nm. Moreover, 76.9% DPPH radical scavenging activity is attained. The synergistic modification with PA and CA effectively improves the overall performance of gelatin films, providing a technical foundation for developing gelatin-based composite functional films.

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王保营, 崔艳勤, 徐 莉, 杨 乐, 杜 闯, 虞安胜, 张 岩.植酸-抗坏血酸钙协同改性明胶复合膜的制备及性能[J].高分子材料科学与工程,2026,42(4):90-99. Baoying Wang, Yanqin Cui, Li Xu, Le Yang, Chuang Du, Ansheng Yu, Yan Zhang. Preparation and Properties of Gelatin Composite Films Synergistically Modified with Phytic Acid and Calcium Ascorbate[J]. Polymer Materials Science & Engineering,2026,42(4):90-99.

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