导热-增强双功能网络构建对聚碳酸酯复合材料性能的影响
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Influence of Constructing Dual-Functional Networks with Enhanced Thermal Conductivity on the Properties of Polycarbonate Composites
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    摘要:

    聚合物内部连续导热网络的构建通常以高填充导热粒子实现,而降低导热粒子逾渗阈值并减小其对材料本身力学性能的破坏是导热聚合物复合材料开发所面临的难题。 为改善聚碳酸酯熔体冷却固化过程的翘曲变形问题并提高聚碳酸酯材料的力学性能,文中利用短切碳纤维为增强填料、球形氧化铝为导热填料,基于不同尺寸形貌功能填料之间的互补协同效应,在降低填料填充量的条件下完成了导热-增强双功能网络构建,实现了改性聚碳酸酯力学性能、导热性能及耐热性能的同步提升。 重点研究了短切碳纤维及球形氧化铝的尺寸及添加量对改性聚碳酸酯复合材料结构与性能的影响,结果表明,碳纤维和球形氧化铝的加入显著提高了聚碳酸酯的力学性能、热变形温度及导热性能,同时显著降低了材料热膨胀系数。 当分别添加质量分数 20% 碳纤维和 20% 球形氧化铝(5 μm)时,复合材料的拉伸强度和弹性模量分别达到 131.6 MPa 和 15.4 GPa,热变形温度提升至 141.1 ℃,导热系数为 0.59 W/ (m·K)。 当球形氧化铝质量分数增加至 50% 时,复合材料在 X,Y 和 Z 3 个方向的热膨胀系数分别降至 7.8×10-6-1, 25.6×10-6-1和 45.9×10-6-1

    Abstract:

    The construction of continuous thermally conductive networks within polymers typically requires high loadings of thermally conductive fillers. Reducing the filler loading threshold while minimizing the detrimental impact on the mechanical properties of the matrix remains a significant challenge in developing thermally conductive polymer composites. To address warpage deformation during the melt cooling and solidification of polycarbonate ( PC) and enhance its mechanical performance, this study employed chopped carbon fibers (CFs) as reinforcing fillers and spherical alumina (Al2O3) particles as thermally conductive fillers. Leveraging the complementary synergistic effects between fillers of different dimensions and morphologies, a dualfunctional network for both thermal conduction and reinforcement was successfully constructed at reduced overall filler content. This approach achieved simultaneous improvements in the mechanical properties, thermal conductivity, and heat resistance of the modified polycarbonate. The study focused on the influence of the size and loading content of chopped carbon fibers and spherical alumina on the structure and properties of the modified PC composites. Results demonstrate that the incorporation of CFs and Al2O3 significantly enhance the mechanical properties, heat deflection temperature (HDT), and thermal conductivity of PC, while also markedly reducing its coefficient of thermal expansion (CTE). With the addition of 20% CFs and 20% spherical Al2O3(5 μm), the composite achieves a tensile strength of 131.6 MPa, a elastic modulus of 15.4 GPa, an HDT of 141.1 ℃, and a thermal conductivity of 0.59 W/ (m·K). When the alumina mass fraction is increased to 50% , the CTE values decrease significantly to 7.8 × 10-6-1, 25.6 × 10-6-1, and 45.9 × 10-6-1 in the X, Y, and Z directions, respectively.

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虞文军, 杨 东, 吕乾龙, 何泰君, 孟令城, 张圣昌, 黄 龙, 刘鹏清.导热-增强双功能网络构建对聚碳酸酯复合材料性能的影响[J].高分子材料科学与工程,2026,42(5):64-72. Wenjun Yu, Dong Yang, Qianlong Lü, Taijun He, Lingcheng Meng, Shengchang Zhang, Long Huang, Pengqing Liu. Influence of Constructing Dual-Functional Networks with Enhanced Thermal Conductivity on the Properties of Polycarbonate Composites[J]. Polymer Materials Science & Engineering,2026,42(5):64-72.

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